| Title | Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2with Epoxides |
|---|---|
| ID_Doc | 14205 |
| Authors | Paradiso, V; Capaccio, V; Lamparelli, DH; Capacchione, C |
| Title | Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2with Epoxides |
| Year | 2020 |
| Published | Catalysts, 10, 8 |
| Abstract | Coupling of CO(2)with epoxides is a green emerging alternative for the synthesis of cyclic organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to provide a comprehensive overview of metal complexes having sulfur-containing ligands as homogeneous catalytic systems able to efficiently promote this transformation with a concise discussion of the most significant results. The crucial role of sulfur as the hemilabile ligand and its influence on the catalytic activity are highlighted as well. |
| https://www.mdpi.com/2073-4344/10/8/825/pdf |
Similar Articles
| ID | Score | Article |
|---|---|---|
7135
|
Della Monica, F; Buonerba, A; Capacchione, C Homogeneous Iron Catalysts in the Reaction of Epoxides with Carbon Dioxide(2019)Advanced Synthesis & Catalysis, 361, 2 | |
| 19807
|
Niknam, F; Capaccio, V; Kleybolte, M; Lamparelli, DH; Winnacker, M; Fiorani, G; Capacchione, C [OSSO]-Type Chromium(III) Complexes for the Reaction of CO2 with Epoxides(2022)Chempluschem, 87.0, 8 |