| Abstract |
Co-pyrolysis of Eucalyptus wood (EW) and Single-use plastic (SUP) can be a sustainable and green technological option ensuring optimum resource recovery and plastic waste management in a circular economy. This study aims to optimize the variables of pyrolysis [temperature (300, 400, 500, 600 degrees C), residence time (90, 120, 150 min), and proportion of plastic (w/w - 0.25, 0.33)] for application of SUP EW char composite in soil. Statistical analysis showed that all three process variables had significant influence on properties of the char. With temperature and residence time, the char became dense, carbonaceous, ash-rich, aromatic, and alkaline for both the proportions of SUP in the feed. Further characterization also revealed that the highest plant extractable concentrations of major nutrients, cation exchange capacity, and electrical conductivity of char composite were recorded with temperatures of 400-500 degrees C, residence time of 120 min, and 33% (w/w) of SUP. The surface morphology analysis revealed the char to have a porous structure with a coating of plastic at lower temperatures of 300 degrees C and an increase in microporosity at higher temperatures of 500, 600 degrees C. Significant positive correlations between radicle root growth and prominent plant growth parameters observed through seed germination test indicate the char's potential applicability in soil. The optimized process parameters of char obtained through regression modeling for application in soil were 415.2 degrees C, 125.2 min, and 0.325 (w/w) proportion of SUP. The highest mean seed length of approximate to 17.5 cm observed at 400 degrees C, 120 min, and 0.33 (w/w) proportion of SUP was consistent with these optimized parameters. Soil incubation test further showed that amendment with optimized char composite significantly improved its properties with a 3.7-fold increase in soil fertility index at 5% rate of application. So, the application of optimized SUP - EW char composite could significantly improve the properties of soil while promoting greener sustainable development through ideal utilization of the so far mismanaged waste resources. (C) 2020 Elsevier Ltd. All rights reserved. |
