Title | Three-dimensional heterostructured MnNiCoP/FeOOH cross-linked nano-flake supported by Ni Foam as a bifunctional electrocatalysts for overall water splitting |
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ID_Doc | 17242 |
Authors | Zhu, LQ; Wang, RZ; Liu, XH; Yang, SH; Liu, HZ; Xing, B; Wang, KK |
Title | Three-dimensional heterostructured MnNiCoP/FeOOH cross-linked nano-flake supported by Ni Foam as a bifunctional electrocatalysts for overall water splitting |
Year | 2024 |
Published | |
Abstract | The production of three-dimensional heterogeneous structures is a vital approach for the creation of high-performance bifunctional electrocatalysts. Herein, three-dimensional heterostructure MnNiCoP/FeOOH (MNC-P/FeOOH) supported by Ni foam was prepared by simple electrodeposition and phosphorylation as a bifunctional electrocatalyst. The results showed that the required overpotential for MNC-P/FeOOH catalyst to reach 100 mA cm(-2) current density was 124 mV and 251 mV in 1.0 M KOH solution, respectively. Construction of heterojunction not only improves the OER performance of MnNiCoP, but also reduces the potential required to drive the integral water splitting at 100 mA cm(-2) current density. The electrocatalytic activity of MNC-P/FeOOH is greatly increased due to a distinctive interface synergy and strong electronic contacts in the MNC-P/FeOOH heterojunction. This design approach of bifunctional transition metal phosphides provides a potential route to achieve total water splitting. |