| Title | Unveiling the Synergistic Effect of Two-Dimensional Heterostructure NiFeP@FeOOH as Stable Electrocatalyst for Oxygen Evolution Reaction |
|---|---|
| ID_Doc | 17309 |
| Authors | Hou, QL; Jiang, ZG; Wang, C; Yang, SH; Liu, HZ; Xing, B; Cheng, HH; Wang, KK |
| Title | Unveiling the Synergistic Effect of Two-Dimensional Heterostructure NiFeP@FeOOH as Stable Electrocatalyst for Oxygen Evolution Reaction |
| Year | 2024 |
| Published | Catalysts, 14, 8 |
| Abstract | Introducing multiple active sites and constructing a heterostructure are efficient strategies to develop high-performance electrocatalysts. Herein, two-dimensional heterostructure NiFeP@FeOOH nanosheets supported by nickel foam (NF) are prepared by a hydrothermal-phosphorization-electrodeposition process. The synthesis of self-supporting heterostructure NiFeP@FeOOH nanosheets on NF increases the specific surface region, while bimetallic phosphide realizes rapid charge transfer, improving the electron transfer rate. The introduction of FeOOH and the construction of a heterostructure result in a synergistic effect among the components, and the surface-active sites are abundant. In situ Raman spectroscopy showed that the excellent oxygen evolution reaction (OER) performance was due to reconstruction-induced hydroxyl oxide, which achieved a multi-active site reaction. The NiFeP@FeOOH/NF electrocatalytic activity was then significantly improved. The findings indicate that in a 1.0 M KOH alkaline solution, NiFeP@FeOOH/NF showed an OER overpotential of 235 mV at 100 mA cm-2, a Tafel slope of 46.46 mV dec-1, and it worked stably at 50 mA cm-2 for 80 h. This research proves that constructing heterostructure and introducing FeOOH are of great significance to the study of the properties of OER electrocatalysts. |
Similar Articles
| ID | Score | Article |
|---|---|---|
17242
|
Zhu, LQ; Wang, RZ; Liu, XH; Yang, SH; Liu, HZ; Xing, B; Wang, KK Three-dimensional heterostructured MnNiCoP/FeOOH cross-linked nano-flake supported by Ni Foam as a bifunctional electrocatalysts for overall water splitting(2024) | |
| 7965
|
Lin, R; Salehi, M; Guo, JX; Seifitokaldani, A High oxidation state enabled by plated Ni-P achieves superior electrocatalytic performance for 5-hydroxymethylfurfural oxidation reaction(2022)Iscience, 25, 8 | |
| 17342
|
Chen, MT; Jiang, ZG; Wang, RZ; Zhu, LQ; Yang, SH; Li, X; Liu, HZ; Zhu, L; Wang, KK Polymetallic Prussian blue analogues with hierarchical structure for high efficiency oxygen evolution reactions(2024) | |
| 6975
|
Han, YJ; Wang, JY; Liu, YH; Li, TQ; Wang, TZ; Li, XY; Ye, XR; Li, GD; Li, JH; Hu, WB; Deng, YD Stability challenges and opportunities of NiFe-based electrocatalysts for oxygen evolution reaction in alkaline media(2024)Carbon Neutralization, 3, 2 |