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Title The Interface Reactions and Solidification Mechanism of Glassy Waste under Hydrothermal Conditions
ID_Doc 17603
Authors Zhu, ZM; Chi, YW; Lin, J; Yao, AH
Title The Interface Reactions and Solidification Mechanism of Glassy Waste under Hydrothermal Conditions
Year 2021
Published Glass Physics And Chemistry, 47, 4
Abstract In this paper, the reaction mechanism of glassy waste in both single-glass and glass-Ca(OH)(2) systems was investigated. However, while adding Ca2+ or Al3+ ions into reaction solutions, the ions interacted with the Si-rich hydrated layer on the surface of glass particles and produced zeolite or anorthite crystals between glass particles. As for glass-Ca(OH)(2) system, besides facilitating the formation of crystals between glass particles, additional Ca2+ or Al3+ ions also promoted the growth of tobermorite or xonotlite crystals at the glass-Ca(OH)(2) interface. In conclusion, the strength of materials was greatly enhanced by strengthening crystal connections in glass particles and at the glass-Ca(OH)(2) interface.
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