| Title | Value-Added Pyrolysis of Waste Sourced High Molecular Weight Hydrocarbon Mixtures |
|---|---|
| ID_Doc | 17979 |
| Authors | Horváth, D; Tomasek, S; Miskolczi, N |
| Title | Value-Added Pyrolysis of Waste Sourced High Molecular Weight Hydrocarbon Mixtures |
| Year | 2022 |
| Published | Energies, 15, 3 |
| Abstract | In this study, Fischer-Tropsch paraffin mixture, heavy residue of waste polyethylene pyrolysis, shredded and crashed agricultural polyethylene waste and their combinations were pyrolysed both thermally and catalytically in a two-stage reactor system. During the experimental work, yields and compositions of pyrolysis products were studied as function of feedstock composition and catalyst placement. It was found that the average molecular weight of feedstocks and the presence of ZSM-5 catalyst also have significant effects on the product yields and the compositions. Feedstocks with high concentration of Fischer-Tropsch paraffin and real waste polyethylene resulted in deeper fragmentation in both thermal and thermo-catalytic pyrolysis. Due to the deeper fragmentation, they seemed to be suitable feedstocks for the production of C-6-C-9 and C-10-C-14 hydrocarbons. Meanwhile, for production of C-15-C-21 hydrocarbons, the use of a higher concentration of heavy residue of waste polyethylene pyrolysis in the feedstocks is recommended. From the point of view of liquid hydrocarbon and isomer production, the placement of the catalyst into the 1st reactor proved to be more advantageous. When the catalyst was placed into the 2nd reactor, the product formation shifted to the more volatiles, isomers took part in secondary cracking reactions and aromatics formed in higher concentrations. |
| https://www.mdpi.com/1996-1073/15/3/997/pdf?version=1643450515 |
Similar Articles
| ID | Score | Article |
|---|---|---|
19156
|
Horváth, D; Tomasek, S; Miskolczi, N Thermo-catalytic co-pyrolysis of waste plastic and hydrocarbon by-products using β-zeolite(2024)Clean Technologies And Environmental Policy, 26.0, 1 | |
| 14828
|
Santos, E; Rijo, B; Lemos, F; Lemos, MANDA A catalytic reactive distillation approach to high density polyethylene pyrolysis - Part 1-Light olefin production(2019) | |
| 12454
|
Peng, YJ; Wang, YP; Ke, LY; Dai, LL; Wu, QH; Cobb, K; Zeng, Y; Zou, RG; Liu, YH; Ruan, RG A review on catalytic pyrolysis of plastic wastes to high-value products(2022) | |
| 26791
|
Cuevas, AB; Leiva-Candia, DE; Dorado, MP An Overview of Pyrolysis as Waste Treatment to Produce Eco-Energy(2024)Energies, 17, 12 | |
| 13475
|
Zhang, JH; Ma, MY; Chen, ZH; Zhang, XY; Yang, H; Wang, XK; Feng, HB; Yu, J; Gao, SQ Production of monocyclic aromatics and light olefins through ex-situ catalytic pyrolysis of low-density polyethylene over Ga/P/ZSM-5 catalyst(2023) | |
| 69576
|
Hussain, I; Ganiyu, SA; Alasiri, H; Alhooshani, K A state-of-the-art review on waste plastics-derived aviation fuel: Unveiling the heterogeneous catalytic systems and techno-economy feasibility of catalytic pyrolysis(2022) | |
| 14449
|
Eschenbacher, A; Varghese, RJ; Abbas-Abadi, MS; Van Geem, KM Maximizing light olefins and aromatics as high value base chemicals via single step catalytic conversion of plastic waste(2022) | |
| 14085
|
Shan, TL; Wang, KS; Li, Y; Gong, Z; Wang, CS; Tian, XL Study on the kinetics of catalytic pyrolysis of single and mixed waste plastics by spent FCC catalyst(2024)Journal Of Thermal Analysis And Calorimetry, 149, 4 | |
| 12306
|
Santos, E; Rijo, B; Lemos, F; Lemos, MANDA A catalytic reactive distillation approach to high density polyethylene pyrolysis-Part 2-Middle olefin production(2021) | |
| 14484
|
Nabgan, W; Ikram, M; Alhassan, M; Owgi, AHK; Tran, TV; Parashuram, L; Nordin, AH; Djellabi, R; Jalil, AA; Medina, F; Nordin, ML Bibliometric analysis and an overview of the application of the non-precious materials for pyrolysis reaction of plastic waste(2023)Arabian Journal Of Chemistry, 16, 6 |