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Title Interaction of sodalite and cancrinite with NH4NO3 solution. First case of low-temperature synthesis of buddingtonite
ID_Doc 18607
Authors Stanimirova, T; Kirov, G
Title Interaction of sodalite and cancrinite with NH4NO3 solution. First case of low-temperature synthesis of buddingtonite
Year 2023
Published
Abstract Hydroxyl sodalite and sulfate cancrinite were synthesized from fly ash from TPP Varna, Bulgaria. The interaction of the two feldspathoids with NH4NO3 solution at 90 degrees C was investigated. Because of the reaction, sodalite is dissolved and ammonium feldspar (buddingtonite) is formed, which is the first case of low-temperature synthesis of this mineral. The interaction of cancrinite with NH4NO3 induces ion exchange and the formation of cancrinite with composition (NH4)5.4Na3.6(NO3)1.45(SO4)0.25(OH)0.05[Al6Si6O24]center dot 2H2O, suggesting potential for the use of this form as a slow-acting fertilizer.
PDF https://doi.org/10.52215/rev.bgs.2023.84.3.55
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