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Title Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples
ID_Doc 19214
Authors Elfadil, D; Della Pelle, F; Compagnone, D; Amine, A
Title Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples
Year 2022
Published Materials, 15.0, 21
Abstract Monitoring synthetic colorants in foods is important due to their potential toxicity and pathogenicity. We propose here a new and simple method for the extraction and determination of erythrosine B (ERT-B) in food samples. A composite of polydopamine-based molecularly imprinted polymers coating magnetic nanoparticles (Fe3O4@PDA@MIP) was synthesized using a green approach and exploited for the magnetic dispersive solid-phase extraction (MDSPE) of ERT-B. Fe3O4@PDA@MIP provides a rapid extraction of ERT-B, exhibiting good reusability and preconcentration ability. Moreover, the MIP showed a relatively good imprinting factor (3.0 +/- 0.05), demonstrating excellent selectivity against patent blue (an interfering dye) and other food matrix components. The proposed MDSPE was coupled to colorimetric smartphone-based detection that allowed us to obtain similar performances of UV-Vis spectroscopy detection. The smartphone-based optical detection facilitated the determination of ERT-B in the 0.5-10 mg/L range, with a limit of detection of 0.04 mg/L. The developed method was successfully employed to determine ERT-B in food samples (juice, candy, and candied cherries) with good recovery values (82-97%).
PDF https://www.mdpi.com/1996-1944/15/21/7653/pdf?version=1667208257
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