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Title Study of the Effect of Leucine on Calcium Carbonate Precipitation in a Circular Economy Perspective
ID_Doc 5153
Authors di Celso, GM; Prisciandaro, M; Karatza, D; Musmarra, D; Lancia, A
Title Study of the Effect of Leucine on Calcium Carbonate Precipitation in a Circular Economy Perspective
Year 2022
Published Water, 14, 2
Abstract This paper studies the crystallization of calcium carbonate in the presence of leucine-a green additive. The effect of leucine on calcium carbonate precipitation kinetic is particularly interesting since CaCO3 is a valuable product worthy to be recovered from industrial liquid wastes (e.g., desalination brines) in the circular economy approach. Experiments have been performed in a laboratory scale plant with a supersaturation range which spams from 2 to 120 and two different leucine concentration (0.520 x 10(-3) and 1.041 x 10(-3) mol/L). Results obtained have been compared with previous published ones, carried out without any additives. From the measurements of induction times for calcium carbonate nucleation, it was established that in solution, the leucine favors the precipitation of calcium carbonate, so it can be considered a promoter in calcium carbonate crystallization and this behavior enhances when raising its concentration in solution. Interfacial tension was determined for both leucine concentration levels, and the values obtained are in the range 51-84 mJ/m(2).
PDF https://www.mdpi.com/2073-4441/14/2/270/pdf?version=1642569015

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28651 di Celso, GM; Prisciandaro, M; Karatza, D; Musmarra, D; Lancia, A Investigating the Effect of Leucine on Calcium Carbonate Nucleation Mechanisms in the View of a Circular Economy(2023)Acs Sustainable Chemistry & Engineering, 11.0, 32
13810 Aghajanian, S; Koiranen, T Dynamic modeling and semibatch reactive crystallization of calcium carbonate through CO2 capture in highly alkaline water(2020)
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