| Title | Cold-plasma activation converting conductive agent in spent Li-ion batteries to bifunctional oxygen reduction/evolution electrocatalyst for zinc-air batteries |
|---|---|
| ID_Doc | 8154 |
| Authors | Liu, YF; Zhuge, XQ; Liu, T; Luo, ZH; Luo, K; Li, YB; Ren, YR; Bayati, M; Liu, XT |
| Title | Cold-plasma activation converting conductive agent in spent Li-ion batteries to bifunctional oxygen reduction/evolution electrocatalyst for zinc-air batteries |
| Year | 2024 |
| Published | |
| Abstract | Considerable amount of high-value transition metals components can be recycled in spent ternary lithium-ion batteries. In this study, we utilized the conductive agent carbon black, obtained from the leaching waste resulting from the chemical recovery of spent lithium-nickel-manganese-cobalt (NCM) oxide cathode materials. This process allows us to create valuable bifunctional catalysts for the oxygen reduction reaction and oxygen evolution reaction (ORR/OER), facilitated by a facile cold plasma activation method, as a part of lithium batteries circular economy. The activated conductive agent (RCA-30) exhibited an ORR half-wave potential of 0.74 V (vs. RHE) in 0.1 mol/L KOH solution, and an OER overpotential of 360 mV at 10 mA cm -2 in 1 mol/L KOH electrolyte, owing to nitrogen doping of carbon black and activation of surface metal oxides. The complete zincair batteries incorporating the activated catalysts at the cathode exhibited an open circuit potential of up to 1.48 V and sustained cycling for 100 h at a current density of 5 mA cm -2 . Additionally, the activated catalysts contributed to a power density of 92 mW cm -2 and a full discharge capacity of 640 mAh/g. |
| https://doi.org/10.1016/j.jcis.2024.03.169 |
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