| Title | Subcritical Water Extraction of Valuable Metals from Spent Lithium-Ion Batteries |
|---|---|
| ID_Doc | 9290 |
| Authors | Lie, JN; Tanda, S; Liu, JC |
| Title | Subcritical Water Extraction of Valuable Metals from Spent Lithium-Ion Batteries |
| Year | 2020 |
| Published | Molecules, 25.0, 9 |
| Abstract | The leaching of valuable metals (Co, Li, and Mn) from spent lithium-ion batteries (LIBs) was studied using subcritical water extraction (SWE). Two types of leaching agents, hydrochloric acid (HCl) and ascorbic acid, were used, and the effects of acid concentration and temperature were investigated. Leaching efficiency of metals increased with increasing acid concentration and temperature. Ascorbic acid performed better than HCl, which was attributed to ascorbic acid's dual functions as an acidic leaching agent and a reducing agent that facilitates leaching reactions, while HCl mainly provides acidity. The chemical analysis of leaching residue by X-ray photoelectron spectroscopy (XPS) revealed that Co(III) oxide could be totally leached out in ascorbic acid but not in HCl. More than 95% of Co, Li, and Mn were leached out from spent LIBs' cathode powder by SWE using 0.2 M of ascorbic acid within 30 min at 100 degrees C, initial pressure of 10 bar, and solid-to-liquid ratio of 10 g/L. The application of SWE with a mild concentration of ascorbic acid at 100 degrees C could be an alternative process for the recovery of valuable metal in spent LIBs. The process has the advantages of rapid reaction rate and energy efficiency that may benefit development of a circular economy. |
| https://www.mdpi.com/1420-3049/25/9/2166/pdf |
Similar Articles
| ID | Score | Article |
|---|---|---|
13980
|
Peng, C; Hamuyuni, J; Wilson, BP; Lundström, M Selective reductive leaching of cobalt and lithium from industrially crushed waste Li-ion batteries in sulfuric acid system(2018) | |
| 68321
|
Sahu, S; Devi, N Hydrometallurgical treatment of spent lithium ion batteries using environmentally friendly leachant and extractant(2023)Journal Of Material Cycles And Waste Management, 25, 6 | |
| 24630
|
Peng, C; Liu, FP; Aji, AT; Wilson, BP; Lundström, M Extraction of Li and Co from industrially produced Li-ion battery waste - Using the reductive power of waste itself(2019) | |
| 23987
|
Pavón, S; Kaiser, D; Bertau, M Recovery of Al, Co, Cu, Fe, Mn, and Ni from spent LIBs after Li selective separation by COOL-Process - Part 2: Solvent Extraction from Sulphate Leaching Solution(2021)Chemie Ingenieur Technik, 93, 11 | |
| 24126
|
Tang, YC; Wang, JZ; Shen, YH Separation of Valuable Metals in The Recycling of Lithium Batteries via Solvent Extraction(2023)Minerals, 13, 2 | |
| 8050
|
Morina, R; Merli, D; Mustarelli, P; Ferrara, C Lithium and Cobalt Recovery from Lithium-Ion Battery Waste via Functional Ionic Liquid Extraction for Effective Battery Recycling(2023)Chemelectrochem, 10, 1 | |
| 21099
|
Aannir, M; Hakkou, R; Levard, C; Taha, Y; Ghennioui, A; Rose, J; Saadoune, I Towards a closed loop recycling process of end-of-life lithium-ion batteries: Recovery of critical metals and electrochemical performance evaluation of a regenerated LiCoO2(2023) | |
| 15043
|
Sethurajan, M; Gaydardzhiev, S Bioprocessing of spent lithium ion batteries for critical metals recovery - A review(2021) | |
| 15446
|
Barrios, OC; Orosco, P; López, CA; Barbosa, LI Recovery of LiCl and Co3O4 from the cathode material contained in spent lithium-ion batteries using chlorination roasting with MgCl2.6H2O(2023) | |
| 12772
|
Biswal, BK; Jadhav, UU; Madhaiyan, M; Ji, LH; Yang, EH; Cao, B Biological Leaching and Chemical Precipitation Methods for Recovery of Co and Li from Spent Lithium-Ion Batteries(2018)Acs Sustainable Chemistry & Engineering, 6.0, 9 |