| Title |
Coral derived nano calcium carbonate incorporated acrylonitrile butadiene rubber composites: Green look at properties |
| ID_Doc |
12295 |
| Authors |
Dominic, CDM; Neenu, KV; Sajadi, SM; Begum, PMS; Gopinath, A; Ragi, AS; Sruthy, S; Dileep, P; Joseph, R; Ilyas, RA; Parameswaranpillai, J |
| Title |
Coral derived nano calcium carbonate incorporated acrylonitrile butadiene rubber composites: Green look at properties |
| Year |
2023 |
| Published |
Journal Of Polymer Research, 30.0, 5 |
| DOI |
10.1007/s10965-023-03544-6 |
| Abstract |
Synthesizing nanofillers from bioresources in a cost-effective way is a practical approach to manage waste and circular economy. This paper highlights the preparation of nano-calcium carbonate (NCC) from dead coral exoskeleton by a simple hydrothermal method. The NCC was characterized using Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and BET surface area analysis. NCC with a particle size of 10-20 nm was obtained by this method. A two-roll mill was used to make the nanocomposites of acrylonitrile-butadiene rubber (NBR) with NCC at various filler concentrations (3, 6, and 9 phr). The cure, physico-mechanical, thermal, swelling, and dynamic properties of the composites were investigated. The mechanical and technological properties of NBR were improved by the incorporation of NCC. About 89% increase in tensile strength was observed with the inclusion of 3 phr NCC to the NBR-Gum. The thermal stability of NBR (T-max) was increased from 450 degrees C to 455 degrees C by the addition of 3 phr NCC. Furthermore, the 9 phr NCC composite showed an 18% lower swelling index and 27% higher crosslink density compared to NBR-Gum. The glass transition temperature of NBR increases from -4.70 to -3.29 degrees C with the addition of 3 phr NCC. The highest Payne effect was observed for NBR-NCC 9 phr composite, indicating effective filler-filler network formation. |
| Author Keywords |
Acrylonitrile-butadiene rubber; Coral reefs; Green chemistry; Hydrothermal method; Nano-CaCO3; Waste management |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Science Citation Index Expanded (SCI-EXPANDED) |
| EID |
WOS:000984540300001 |
| WoS Category |
Polymer Science |
| Research Area |
Polymer Science |
| PDF |
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