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Title Eco-friendly Selective Synergistic Extraction Rare-Earths from Waste CRT Phosphor Powder Sulfuric Acid Leachate with Imidazolium-Based Ionic Liquid [OMIm] [PF6] and Extractant Cyanex272
ID_Doc 12767
Authors Tian, XM; Wu, YF; Yin, XF; Gong, Y; Zhang, KH; Fu, Y
Title Eco-friendly Selective Synergistic Extraction Rare-Earths from Waste CRT Phosphor Powder Sulfuric Acid Leachate with Imidazolium-Based Ionic Liquid [OMIm] [PF6] and Extractant Cyanex272
Year 2018
Published
DOI 10.1007/978-981-13-0158-2_52
Abstract Considering the benefits of resource, environment and economy, recycling secondary rare earth resources is becoming an extremely significant resource regeneration way. In this paper, we reported a novel synergistic extraction system combining ionic liquid [OMIm] [PF6] and extractant Cyanex272 to separate and purify the REE from the leachate of waste CRT phosphor powder. Some extraction parameters were studied including extraction acidity, the ratio of organic phase to aqueous phase, the ratio of Cyanex272 and [OMIm] [PF6], extraction time and extraction temperature. The optimal parameters of the extraction process was obtained as extraction acidity 0.2 mol/L, the ratio of organic phase to aqueous phase 1:5, the ratio of Cyanex272 and [OMIm]PF6 X-C = 0.4, extraction time 10 min and extraction temperature 25 degrees C. Under these conditions, REE is successfully and efficiently extracted and separated with zinc and aluminum, which revealed a potential application for REE separation and purification from electronic waste.
Author Keywords Ionic liquid extraction; Rare earth; CRT phosphor powder
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Conference Proceedings Citation Index - Science (CPCI-S)
EID WOS:000541673800052
WoS Category Energy & Fuels; Environmental Sciences
Research Area Energy & Fuels; Environmental Sciences & Ecology
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