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Title Influence of nucleating agent on the mechanical and thermal properties of neat isotactic polypropylene/reprocessed polypropylene blends
ID_Doc 12960
Authors Berktas, ME; Ekinci, A; Oksuz, M; Ates, M; Aydin, I
Title Influence of nucleating agent on the mechanical and thermal properties of neat isotactic polypropylene/reprocessed polypropylene blends
Year 2024
Published
DOI 10.1007/s13726-024-01369-8
Abstract In recent years, recycling of polypropylene (PP) has gained significant attention for various industrial applications, namely post-industrial PP waste has great advantages in terms of circular economy. In this study, the effect of the amount of nucleating agent on the mechanical and thermal properties of polypropylene blends was investigated. Neat isotactic polypropylene and reprocessed polypropylene (iPP/rPP) were blended by means of a twin-screw extruder at 0/100, 50/50, 25/75 and 100/0% (by weight), respectively. The blends were processed by means of a twin-screw extruder then injection molded with the nucleating agent at different ratios (0, 1, 3 and 6% by weight). The properties of the samples were investigated by melt flow index (MFI) measurement, scanning electron microscope (SEM), tensile test, three point bending test and differential scanning calorimetry (DSC) analysis. The MFI values of the blends increased with the increasing amount of rPP. As a result of DSC analysis, the melting temperature of the blends increased by 1.4 degrees C with the presence of 6% (by weight) nucleating agent. The highest flexural modulus was obtained as 1863 MPa for the iPP/rPP0 blends with the addition of 6% (by weight) nucleating agent. The elastic modulus increased with the addition of nucleating agent from 1819 (iPP/rPP50NA0) to 2152 MPa (iPP/rPP50NA6). The iPP/rPP blend with a weight ratio of (50/50) exhibited mechanical and thermal properties similar to neat iPP with the presence of 3% (by weight) nucleating agent.
Author Keywords rPP; Nucleating agent; Injection molding; Recycling; Post-industrial waste
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:001309265400001
WoS Category Polymer Science
Research Area Polymer Science
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