| Abstract |
Improving phosphorus (P) use efficiency is a challenge to promote a circular economy and greening the phosphorus cycle towards planetary sustainability. The disruptive innovation for phosphate fertilizers may help to reduce some unwelcome reactions that occur to Pin soils. Monoammonium phosphate (MAP) coating with biodegradable organic polymers and the addition of magnesium (Mg) - a nutrient with a synergistic effect on the uptake of P, zinc (Zn), and boron (B) - emerge as a smart strategy to applying these micronutrients uniformly in soils. The objectives of this study were: to characterize the coated-MAP with biodegradable organic polymers, quantify the diffusion and availability of P in the soil, and evaluate the corn crop nutrition and yield during two crop seasons. The treatments were: MAP, MAP coated with biodegradable organic polymer (BOP), MAP + BOP - 1.3% of Zn + 033% of B, and MAP + BOP + 1.76% of Mg. The laboratory tests showed that the diffusion of MAP-based fertilizers was: MOMg (7.86 mm) = MO (8.82 mm) = MAP (8.84 mm) = MOM (8.51 mm) after 432 h. Coatings did not cause delays in the P-release in water at 25 degrees C since more than 95% of P was released within 24 h. In the field trials, the application of Mg, Zn, and B in the MAP coating did not increase nutrient leaf concentration. In the summer crop season, grain yield increased up to the P-rates of 85 kg of P2O5 ha(-1), reaching the value of 6731 kg ha(-1). Physical and chemical characteristics of MAP-fertilizers tend to improve with the coatings. The addition of biodegradable organic polymers, Mg, B, and Zn, as MAP-coatings did not enhance P diffusion, release, and availability in the soil and the crop nutrition. Coated-MAP improved corn yield only in the 2nd crop season. (C) 2021 Elsevier B.V. All rights reserved. |