| Title |
Eco-Friendly Dye Adsorbent from Poly(vinyl amine) Grafted Onto Bacterial Cellulose Sheet by Using Gamma Radiation-Induced Simultaneous Grafting and Base Hydrolysis |
| ID_Doc |
17199 |
| Authors |
Rattanawongwiboon, T; Khongbunya, N; Namvijit, K; Lertsarawut, P; Laksee, S; Hemvichian, K; Madrid, JF; Ummartyotin, S |
| Title |
Eco-Friendly Dye Adsorbent from Poly(vinyl amine) Grafted Onto Bacterial Cellulose Sheet by Using Gamma Radiation-Induced Simultaneous Grafting and Base Hydrolysis |
| Year |
2024 |
| Published |
Journal Of Polymers And The Environment, 32, 7 |
| DOI |
10.1007/s10924-023-03140-1 |
| Abstract |
N-vinylformamide (NVF) was successfully grafted onto a bacterial cellulose (BC) sheet through gamma radiation-induced simultaneous grafting. The optimum conditions for grafting were an irradiation dose of 15 kGy and an NVF concentration of 30%vol. The resulting product, poly(vinyl formamide)-grafted-bacterial cellulose sheet (PNVF-g-BC) was hydrolyzed using a basic medium to obtain poly(vinyl amine)-grafted-BC (PVAm-g-BC) as an eco-friendly dye adsorbent. The maximum degrees of NVF grafting and hydrolysis were 98.89 +/- 3.95% and 88 +/- 0.55%, respectively. Chemical, binding energy, crystalline, thermal, and morphological characterizations of the starting materials, as well as PNVF-g-BC and PVAm-g-BC adsorbents, were conducted. Batch tests were performed to investigate the efficiency of methylene blue (MB) adsorption and the adsorption capacity of the PVAm-g-BC adsorbent. The effects of initial MB concentration, time, and pH on the adsorption were studied. The maximum adsorption capacity of the adsorbent was 7.78 +/- 0.41 mg/g at an MB concentration of 10 mg/L, pH 13, and a reaction time of 8 h. The adsorption behavior of MB onto the adsorbent was found to fit the Langmuir isotherm model, indicating monolayer adsorption. The adsorption/desorption study demonstrated that the adsorbents could be reused for 6 cycles with effective performance for MB adsorption (> 50%). This eco-friendly dye adsorbent exhibits outstanding properties as a potential candidate for dye adsorption. |
| Author Keywords |
Bacterial cellulose; Radiation-induced grafting; Dye adsorption |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Science Citation Index Expanded (SCI-EXPANDED) |
| EID |
WOS:001132062200003 |
| WoS Category |
Engineering, Environmental; Polymer Science |
| Research Area |
Engineering; Polymer Science |
| PDF |
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