Title |
Novel integrated mechanical biological chemical treatment (MBCT) systems for the production of levulinic acid from fraction of municipal solid waste: A comprehensive techno-economic analysis |
ID_Doc |
17237 |
Authors |
Sadhukhan, J; Ng, KS; Martinez-Hernandez, E |
Title |
Novel integrated mechanical biological chemical treatment (MBCT) systems for the production of levulinic acid from fraction of municipal solid waste: A comprehensive techno-economic analysis |
Year |
2016 |
Published |
|
DOI |
10.1016/j.biortech.2016.04.030 |
Abstract |
This paper, for the first time, reports integrated conceptual MBCT/biorefinery systems for unlocking the value of organics in municipal solid waste (MSW) through the production of levulinic acid (LA by 5 wt%) that increases the economic margin by 110-150%. After mechanical separation recovering recyclables, metals (iron, aluminium, copper) and refuse derived fuel (RDF), lignocelluloses from remaining MSW are extracted by supercritical-water for chemical valorisation, comprising hydrolysis in 2 wt% dilute H2SO4 catalyst producing LA, furfural, formic acid (FA), via C-5/C-6 sugar extraction, in plug flow (210-230 degrees C, 25 bar, 12 s) and continuous stirred tank (195-215 degrees C, 14 bar, 20 min) reactors; char separation and LA extraction/purification by methyl isobutyl ketone solvent; acid/solvent and by-product recovery. The by-product and pulping effluents are anaerobically digested into biogas and fertiliser. Produced biogas (6.4 MWh/t), RDF (5.4 MWh/t), char (4.5 MWh/t) are combusted, heat recovered into steam generation in boiler (efficiency: 80%); on-site heat/steam demand is met; balance of steam is expanded into electricity in steam turbines (efficiency: 35%). (C) 2016 Elsevier Ltd. All rights reserved. |
Author Keywords |
Circular economy; Metal and energy and material resource recovery from MSW; Municipal solid waste management; Combined heat and power (CHP), Refuse derived fuel (RDF) and compost like output (CLO); Biorefinery process simulation in Aspen Plus(C), Value analysis and discounted cash flow (DCF) analysis |
Index Keywords |
Index Keywords |
Document Type |
Other |
Open Access |
Open Access |
Source |
Science Citation Index Expanded (SCI-EXPANDED) |
EID |
WOS:000377935100016 |
WoS Category |
Agricultural Engineering; Biotechnology & Applied Microbiology; Energy & Fuels |
Research Area |
Agriculture; Biotechnology & Applied Microbiology; Energy & Fuels |
PDF |
http://opus.bath.ac.uk/51474/1/integrated_mechanical_biological_chemical_treatment_systems_for_the_production_of_levulinic_acid_from_municipal_solid_waste_ACCEPTED.docx
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