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Title Effects of multi-walled carbon nanotubes on structures and properties of heat-resistant poly(m-phenylene isophthalamide)-based hollow fiber ultrafiltration membranes
ID_Doc 18189
Authors Koo, SH; Jee, MH; Baik, DH
Title Effects of multi-walled carbon nanotubes on structures and properties of heat-resistant poly(m-phenylene isophthalamide)-based hollow fiber ultrafiltration membranes
Year 2024
Published Polymer Engineering And Science, 64.0, 2
DOI 10.1002/pen.26565
Abstract This study is the first attempt to fabricate a heat-resistant hollow fiber ultrafiltration membrane using poly(m-phenylene isophthalamide) (PMIA) polymer material, which has rarely been used as conventional polymeric membrane materials. Multi-walled carbon nanotubes (MWCNTs) are incorporated as reinforcing agents. The PMIA polymer synthesized for this study exhibited an inherent viscosity of 1.6 dL/g, confirming its suitability for membrane fabrication, and successful synthesis was verified through Fourier-transform infrared analysis. To enhance the dispersibility of MWCNTs during dope solution preparation and their interaction with the PMIA matrix, MWCNTs were acid-treated and surface characteristics of the acid-treated MWCNTs were confirmed through x-ray photoelectron spectroscopy analysis. Scanning electron microscope analysis revealed that the introduction of MWCNTs resulted in thicker PMIA hollow fiber ultrafiltration membranes with symmetrical finger-like and sponge-like pore structures. Interestingly, unlike the typical polymer composite systems containing MWCNTs, which often show a dependence on MWCNT content, the mechanical properties of the PMIA/MWCNT membranes in this study seem to exhibit high variability and are not contingent on the MWCNT content. Additionally, filtration performance studies demonstrated that the introduction of MWCNTs substantially increased water permeability, particularly at 1.0 wt% MWCNT content, resulting in a remarkable 130% enhancement compared to pristine PMIA membrane. Simultaneously, even with a small quantity of MWCNTs, the rejection performance of the PMIA/MWCNT membrane witnessed significant improvement due to the reduction in average pore size, effectively overcoming the commonly observed trade-off phenomenon. In summary, this study clearly showed the effects and changes on the structure and properties of a heat-resistant PMIA-based hollow fiber ultrafiltration membranes due to the introduction of MWCNTs.
Author Keywords enhanced mechanical properties; heat-resistant hollow fiber ultrafiltration membrane; MWCNTs; poly(m-phenylene isophthalamide) (PMIA); simultaneous improvement of water permeability and rejection
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:001107566000001
WoS Category Engineering, Chemical; Polymer Science
Research Area Engineering; Polymer Science
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