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Title Development of clove oil based nanoencapsulated biopesticide employing mesoporous nanosilica synthesized from paddy straw via bioinspired sol-gel route
ID_Doc 21119
Authors Singh, G; Arora, H; Hariprasad, P; Sharma, S
Title Development of clove oil based nanoencapsulated biopesticide employing mesoporous nanosilica synthesized from paddy straw via bioinspired sol-gel route
Year 2023
Published
DOI 10.1016/j.envres.2022.115208
Abstract Paddy straw (PS) burning is a concerning issue in South Asian countries, clamoring for exploring alternative management strategies. Being a rich source of silica, PS can be a potential nanosilica (SiNPs) source. The current study reports a pioneering approach for green synthesis of high-purity mesoporous SiNPs by sol-gel method using the aqueous extract of Sapindus mukorossi seed pericarp as a stabilizer. The mesoporous nature of SiNPs was harnessed as a carrier for the essential oil to develop the carrier-based formulation. SiNPs were characterized using XRD, EDX, FTIR, FE-SEM, TEM, AFM, DLS, water contact angle, and BET analysis. The synthesized SiNPs possessed a spheroid morphology with an average particle size of 20.34 +/- 2.64 nm. XRD results confirmed its amorphous nature. The mesoporous nature of SiNPs was confirmed using BET analysis which showed a cumu-lative pore volume of 2.059 cm3/g and a high surface area of 746.32 m2/g. The SiNPs were further loaded with clove essential oil (CEO), and the encapsulation of CEO was assessed using UV-Vis, FTIR, and BET analysis. The in-vitro antifungal activity of CEO and CEO-loaded SiNPs (CEO-SiNPs) was evaluated using the agar plate assay. UV-Vis results depicted 62.64% encapsulation of CEO in SiNPs. The antifungal efficacy of CEO-SiNPs against F. oxysporum exhibited minimum inhibitory concentration (MIC), i.e., 125 mg/L, while the MIC of CEO was found to be 250 mg/L. The study delivers new insights into the holistic utilization of PS and propitious contribution toward the circular economy and Sustainable Development Goals (SDGs).
Author Keywords Paddy straw; Silica nanoparticles; Sapindus mukorossi; nanoencapsulation; SDGs; Circular economy
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:000918338500001
WoS Category Environmental Sciences; Public, Environmental & Occupational Health
Research Area Environmental Sciences & Ecology; Public, Environmental & Occupational Health
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