Title |
Recovery of lithium and cobalt from lithium cobalt oxide and lithium nickel manganese cobalt oxide batteries using supercritical water |
ID_Doc |
24121 |
Authors |
Barros, TV; Notario, VA; de Oliveira, JA; Bispo, DF; Freitas, LD; Jegatheesan, V; Cardozo, L |
Title |
Recovery of lithium and cobalt from lithium cobalt oxide and lithium nickel manganese cobalt oxide batteries using supercritical water |
Year |
2024 |
Published |
|
DOI |
10.1016/j.envpol.2024.124570 |
Abstract |
This study investigates the eco-friendly extraction of metal oxides from LCO and NMC batteries using supercritical water. Experiments were conducted at 450 degrees C with a feed rate of 5 mL min(-1) and varying battery/PVC ratios (0.0, 2.0, and 3.0). The products were analyzed by X-ray diffractometry (XRD), atomic absorption spectrometry (FAAS) and gas chromatography-mass spectrometry (GC-MS). Results show the presence of cobalt chloride (CoCl2) and lithium (Li) in the liquid products, achieving 100% cobalt recovery under all conditions. The gaseous products obtained hydrogen with molar compositions up to 78.3% and 82.7% for LCO:PVC and NMC:PVC batteries, respectively, after 60 min of reaction. These findings highlight the potential of this methodology for lithium-ion battery recycling. |
Author Keywords |
Li-ion; SCW; PVC; batteries; cobalt; Circular economy |
Index Keywords |
Index Keywords |
Document Type |
Other |
Open Access |
Open Access |
Source |
Science Citation Index Expanded (SCI-EXPANDED) |
EID |
WOS:001278840200001 |
WoS Category |
Environmental Sciences |
Research Area |
Environmental Sciences & Ecology |
PDF |
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