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Scientific Article details

Title Life Cycle Assessment of Polyol Production from Lignin via Organosolv and Liquefaction Treatments
ID_Doc 24552
Authors Cavalaglio, G; Mecca, I; Iodice, P; Giannoni, T; Gelosia, M; Nicolini, A; Temporim, RBL; Johnson, EP
Title Life Cycle Assessment of Polyol Production from Lignin via Organosolv and Liquefaction Treatments
Year 2023
Published Sustainability, 15, 22
DOI 10.3390/su152215905
Abstract This study aimed to conduct a comprehensive Life Cycle Assessment (LCA) of lignin-based polyol production through organosolv fractionation of cardoon stalks and subsequent lignin liquefaction. The LCA employed a cradle-to-gate approach, encompassing cardoon cultivation and all processing steps leading to polyol production. The research involved laboratory-scale optimization of the organosolv and liquefaction processes, followed by industrial-scale implementation. The analysis revealed that all stages of the production chain, including crop cultivation, organosolv, and liquefaction, significantly influenced overall environmental impacts. Specific materials and processes played pivotal roles, such as harvesting machinery and fertilizers in crop production, gamma-Valerolactone (GVL) as the primary contributor (72-100%) to environmental impacts in the organosolv phase, and materials like polyethylene glycol 400 (PEG 400) and glycerin in the liquefaction phase, accounting for the majority (96-100%) of environmental impacts in this stage. When considering endpoint damage categories, it became evident that this production chain had a notable impact on human health, primarily due to emissions in air, water, and soil from agricultural processes. Lignin-based polyols demonstrated a moderate improvement compared to their petroleum-based counterparts, with an approximate reduction of 3-16% in environmental impact.
Author Keywords polyol; life cycle assessment; organosolv lignin; circular economy; biomaterial
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED); Social Science Citation Index (SSCI)
EID WOS:001120929600001
WoS Category Green & Sustainable Science & Technology; Environmental Sciences; Environmental Studies
Research Area Science & Technology - Other Topics; Environmental Sciences & Ecology
PDF https://www.mdpi.com/2071-1050/15/22/15905/pdf?version=1699934996
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