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Title The Viable Fabrication of Gas Separation Membrane Used by Reclaimed Rubber from Waste Tires
ID_Doc 25659
Authors Lin, YT; Zhuang, GL; Wey, MY; Tseng, HH
Title The Viable Fabrication of Gas Separation Membrane Used by Reclaimed Rubber from Waste Tires
Year 2020
Published Polymers, 12, 11
DOI 10.3390/polym12112540
Abstract Improper disposal and storage of waste tires poses a serious threat to the environment and human health. In light of the drawbacks of the current disposal methods for waste tires, the transformation of waste material into valuable membranes has received significant attention from industries and the academic field. This study proposes an efficient and sustainable method to utilize reclaimed rubber from waste tires after devulcanization, as a precursor for thermally rearranged (TR) membranes. The reclaimed rubber collected from local markets was characterized by thermogravimetric analyzer (TGA) and Fourier transfer infrared spectroscopy (FT-IR) analysis. The results revealed that the useable rubber in the as-received sample amounted to 57% and was classified as styrene-butadiene rubber, a type of synthetic rubber. Moreover, the gas separation measurements showed that the C7-P2.8-T250 membrane with the highest H-2/CO2 selectivity of 4.0 and sufficient hydrogen permeance of 1124.61 GPU exhibited the Knudsen diffusion mechanism and crossed the Robeson trade-off limit. These findings demonstrate that reclaimed rubber is an appealing, cost effective, and sustainable alternative, as a precursor for TR membranes, for application in gas separation. The present approach is useful in the selection of a suitable reclaimed rubber precursor and related membrane preparation parameters, leading to the advancement in the recycling value of waste tires.
Author Keywords gas separation; thermally rearranged membrane; waste material; sustainable development; circular economy
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:000594367500001
WoS Category Polymer Science
Research Area Polymer Science
PDF https://www.mdpi.com/2073-4360/12/11/2540/pdf?version=1604045441
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