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Title Carbonized Solid Fuel Production from Polylactic Acid and Paper Waste Due to Torrefaction
ID_Doc 26632
Authors Swiechowski, K; Zafiu, C; Bialowiec, A
Title Carbonized Solid Fuel Production from Polylactic Acid and Paper Waste Due to Torrefaction
Year 2021
Published Materials, 14, 22
DOI 10.3390/ma14227051
Abstract The quantity of biodegradable plastics is increasing steadily and taking a larger share in the residual waste stream. As the calorific value of biodegradable plastic is almost two-fold lower than that of conventional ones, its increasing quantity decreases the overall calorific value of municipal solid waste and refuse-derived fuel which is used as feedstock for cement and incineration plants. For that reason, in this work, the torrefaction of biodegradable waste, polylactic acid (PLA), and paper was performed for carbonized solid fuel (CSF) production. In this work, we determined the process yields, fuel properties, process kinetics, theoretical energy, and mass balance. We show that the calorific value of PLA cannot be improved by torrefaction, and that the process cannot be self-sufficient, while the calorific value of paper can be improved up to 10% by the same process. Moreover, the thermogravimetric analysis revealed that PLA decomposes in one stage at similar to 290-400 degrees C with a maximum peak at 367 degrees C, following a 0.42 reaction order with the activation energy of 160.05 kJ.(mol.K)(-1).
Author Keywords torrefaction; solid fuel; waste to carbon; circular economy; biodegradable materials; calorific value
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:000765718300001
WoS Category Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering; Physics, Applied; Physics, Condensed Matter
Research Area Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics
PDF https://www.mdpi.com/1996-1944/14/22/7051/pdf?version=1637409742
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