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Title Production of Cellulose Nanofibers from Olive Tree Harvest-A Residue with Wide Applications
ID_Doc 26734
Authors Sánchez-Gutiérrez, M; Espinosa, E; Bascón-Villegas, I; Pérez-Rodríguez, F; Carrasco, E; Rodríguez, A
Title Production of Cellulose Nanofibers from Olive Tree Harvest-A Residue with Wide Applications
Year 2020
Published Agronomy-Basel, 10, 5
DOI 10.3390/agronomy10050696
Abstract With the aim of identifying new sources to produce cellulose nanofibers, olive tree pruning biomass (OTPB) was proposed for valorization as a sustainable source of cellulose. OTPB was subjected to a soda pulping process for cellulose purification and to facilitate the delamination of the fiber in the nanofibrillation process. Unbleached and bleached pulp were used to study the effect of lignin in the production of cellulose nanofibers through different pretreatments (mechanical and TEMPO-mediated oxidation). High-pressure homogenization was used as the nanofibrillation treatment. It was observed that for mechanical pretreatment, the presence of lignin in the fiber produces a greater fibrillation, resulting in a smaller width than that achieved with bleached fiber. In the case of TEMPO-mediated oxidation, the cellulose nanofiber characteristics show that the presence of lignin has an adverse effect on fiber oxidation, resulting in lower nanofibrillation. It was observed that the crystallinity of the nanofibers is lower than that of the original fiber, especially for unbleached nanofibers. The residual lignin content resulted in a greater thermal stability of the cellulose nanofibers, especially for those obtained by TEMPO-mediated oxidation. The characteristics of the cellulose nanofibers obtained in this work identify a gateway to many possibilities for reinforcement agents in paper suspension and polymeric matrices.
Author Keywords olive tree harvest; lignocellulose nanofibers; circular economy; valorization; pretreatments; high-pressure homogenization
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:000541750900049
WoS Category Agronomy; Plant Sciences
Research Area Agriculture; Plant Sciences
PDF https://www.mdpi.com/2073-4395/10/5/696/pdf?version=1590679986
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