Title |
Effective Thermal-Oxidative Reclamation of Waste Tire Rubbers for Producing High-Performance Rubber Composites |
ID_Doc |
29830 |
Authors |
Zhang, YX; Zhang, Z; Wemyss, AM; Wan, CY; Liu, YT; Song, P; Wang, SF |
Title |
Effective Thermal-Oxidative Reclamation of Waste Tire Rubbers for Producing High-Performance Rubber Composites |
Year |
2020 |
Published |
Acs Sustainable Chemistry & Engineering, 8.0, 24 |
DOI |
10.1021/acssuschemeng.0c02292 |
Abstract |
The disposal and accumulation of waste tire rubbers has a significant negative impact on the development of a circular economy and sustainable environment. To reuse and recycle ground tire rubber, we developed a thermal-oxidative reclamation process using a newly designed dynamic reclamation reactor. In the absence of any chemical agent, a high scission efficiency was achieved at a sol fraction of 66.53 wt % at 200 degrees C after 20 min from the thermal oxidation of GTR. The physical and chemical structural evolutions of GTR during the thermo-oxidation process were systemically investigated by monitoring the Mooney viscosity, sol-gel ratio, molecular weight, and chemical structure changes. The reclaimed ground tire rubber containing ultrafine fillers and soluble elastomer can be easily dispersed into a natural rubber matrix. The mechanical properties and aging resistance of the modified natural rubber were enhanced with the addition of up to 40 wt % reclaimed ground tire rubber. This work demonstrates a green and up-scalable approach for reclamation and reuse of waste tire rubbers for a sustainable rubber industry. |
Author Keywords |
Ground tire rubber; Thermal-oxidative reclamation; High scission; Natural rubber; Mechanical properties |
Index Keywords |
Index Keywords |
Document Type |
Other |
Open Access |
Open Access |
Source |
Science Citation Index Expanded (SCI-EXPANDED) |
EID |
WOS:000543715400021 |
WoS Category |
Chemistry, Multidisciplinary; Green & Sustainable Science & Technology; Engineering, Chemical |
Research Area |
Chemistry; Science & Technology - Other Topics; Engineering |
PDF |
http://wrap.warwick.ac.uk/137231/1/WRAP-Effective-thermal-oxidative-reclamation-waste-tire-rubbers-composites-Wan-2020.pdf
|