| Title |
Facile synthesis of zirconia doped hybrid organic inorganic silica membranes |
| ID_Doc |
64161 |
| Authors |
ten Hove, M; Nijmeijer, A; Winnubst, L |
| Title |
Facile synthesis of zirconia doped hybrid organic inorganic silica membranes |
| Year |
2015 |
| Published |
|
| DOI |
10.1016/j.seppur.2014.12.033 |
| Abstract |
Hybrid organic inorganic silica membranes are interesting candidates for gas-separation applications due to their excellent hydrothermal stability. However, up to now these membranes lack the separation performance required to separate hydrogen from carbon dioxide. In this work a procedure for doping zirconia into the hybrid silica matrix is reported, resulting in an improved H-2/CO2 permselective membrane compared with non-doped hybrid silica membranes. Zirconia doped 1,2-bis(triethoxysilyl)ethane (Zr-BTESE) was synthesized by sal-gel chemistry, using zirconyl nitrate as the zirconium source. By optimization of the sol reaction conditions (i.e. reaction time and temperature) a homogenous sol was obtained. Defect-free membranes were obtained by adjusting the concentration of the dip-coating solution. The doped membranes showed a slight decrease in hydrogen permeance from 4.4 x 10(-7) to 1.8 x 10(-7) mol m(-2) S-1 Pa-1 as compared to an undoped BTESE membrane, but a large increase in H-2/CO2 (from 4 to 16) and H-2/N-2 (from 12 to 100) permselectivity was observed. (C) 2015 Elsevier B.V. All rights reserved. |
| Author Keywords |
Gas separation; Hybrid silica; Metal doping; Sol-gel |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Science Citation Index Expanded (SCI-EXPANDED) |
| EID |
WOS:000356553300042 |
| WoS Category |
Engineering, Chemical |
| Research Area |
Engineering |
| PDF |
https://research.utwente.nl/files/6491246/1-s2.0-S1383586615000106-main.pdf
|