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Title Recycling of silicon solar panels through a salt-etching approach
ID_Doc 8409
Authors Gao, SB; Chen, X; Qu, JK; Guo, YY; Shi, H; Pang, FZ; Guo, L; Qu, X; Wang, DH; Yin, HY
Title Recycling of silicon solar panels through a salt-etching approach
Year 2024
Published Nature Sustainability, 7.0, 7
DOI 10.1038/s41893-024-01360-4
Abstract The production and use of silicon (Si) solar panels is soaring during the transition to a carbon-neutral energy system. To mitigate their environmental footprints, there is an urgent need to develop an efficient recycling method to handle end-of-life Si solar panels. Here we report a simple salt-etching approach to recycle Ag and Si from end-of-life Si solar panels without using toxic mineral acids and generating secondary pollution. The etching process is enabled by the high corrosivity of molten hydroxide that spontaneously reacts with SiNx, SiO2, Al2O3 and Al at the surface of Si wafers through the top-down direction, thereby directly separating Ag from Si wafers. The etching process takes only 180 s to recover >99.0% of Ag and >98.0% of Si from end-of-life Si solar panels. In addition, Cu, Pb, Sn and Al in Si solar panels are also recovered through a combined oxidation, alkaline leaching and electrodeposition approach. Overall, this study presents a viable approach for sustainable management of end-of-life Si solar panels, paving the way to a circular economy.
Author Keywords
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED); Social Science Citation Index (SSCI)
EID WOS:001238183400001
WoS Category Green & Sustainable Science & Technology; Environmental Sciences; Environmental Studies
Research Area Science & Technology - Other Topics; Environmental Sciences & Ecology
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