| Title |
Interplay Between Particle Size and Hierarchy of Zeolite ZSM-5 During the CO2-to-aromatics Process |
| ID_Doc |
8828 |
| Authors |
Liu, K; Ramirez, A; Zhang, X; Çaglayan, M; Gong, X; Gascon, J; Chowdhury, AD |
| Title |
Interplay Between Particle Size and Hierarchy of Zeolite ZSM-5 During the CO2-to-aromatics Process |
| Year |
2023 |
| Published |
Chemsuschem, 16.0, 19 |
| DOI |
10.1002/cssc.202300608 |
| Abstract |
The CO2-to-aromatics process is a chemical reaction that converts carbon dioxide (CO2) into valuable petrochemical, i. e., aromatics (especially, benzene, toluene, and xylene) over the metal/zeolite bifunctional catalytic systems. These aromatics are used in producing plastics, fibers, and other industrial products, which are currently exclusively sourced from fossil-derived feedstocks. The significance of this process lies in its potential to mitigate climate change by reducing greenhouse gas emissions and simultaneously producing valuable chemicals. Consequently, these CO2-derived aromatics can reduce the reliance on fossil fuels as a source of feedstocks, which can help to promote a more sustainable and circular economy. Owing to the existence of a wider straight channel favoring the aromatization process, zeolite ZSM-5 is extensively used to yield aromatics during CO2 hydrogenation over bifunctional (metal/zeolite) catalytic systems. To provide a better understanding of this unique property of zeolite ZSM-5, this work investigates the impact of particle size and hierarchy of the zeolite and how these govern the reaction performance and the overall selectivity. As a result, an improved understanding of the zeolite-catalyzed hydrocarbon conversion process has been obtained. |
| Author Keywords |
CO2 valorization; Zeolite; Petrochemicals; Bifunctional Catalysis; Fischer-Tropsch synthesis |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Science Citation Index Expanded (SCI-EXPANDED) |
| EID |
WOS:001037863000001 |
| WoS Category |
Chemistry, Multidisciplinary; Green & Sustainable Science & Technology |
| Research Area |
Chemistry; Science & Technology - Other Topics |
| PDF |
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