| Title | Removal of toxic dye from dye-laden wastewater using a new nanocomposite material: Isotherm, kinetics and adsorption mechanism |
|---|---|
| ID_Doc | 28006 |
| Authors | Shaikh, WA; Kumar, A; Chakraborty, S; Naushad, M; Ul Islam, R; Bhattacharya, T; Datta, S |
| Title | Removal of toxic dye from dye-laden wastewater using a new nanocomposite material: Isotherm, kinetics and adsorption mechanism |
| Year | 2022 |
| Published | |
| Abstract | In this study, (hemi)cellulosic biochar-based environment-friendly non-toxic nanocomposite (nAg-AC) was fabricated for an inordinate overlook of toxic dye-laden wastewater depollution. This hybrid nanocomposite grafted with silver nanoparticles, numerous hydroxyl and 7C-bond containing functional groups exhibited outstanding physicochemical properties. FESEM images indicated the heterogeneous porous structure of nAg-AC, while BET analysis revealed mesoporous property with a significant increment of overall surface area (132%). Imbedding of silver nanoparticles and the presence of multiple hydroxyl groups was evident from the XRD and XPS spectrum. Further, the TGA result indicated excellent thermal stability, and FTIR analysis suggested the involvement of surface functional groups like -OH, =C = O, =NH, =C = C = , and -CH in Rhodamine B (RhB) adsorption. The adsorbent matrix provided the overall mechanical strength and facilitated recycling, while the functional matrix (biochar) provided the adsorptive locus for augmented RhB adsorption efficiency (92.77%). Experiments pertaining to adsorption isotherms and kinetics modeling suggested that RhB was removed through multilayer chemisorption on the heterogeneous nAg-AC surface. The main RhB adsorption mechanism included cumulative efforts of H-bindings, 7C-7C stacking interaction, pore-filling, and electrostatic interactions. The nAg-AC maintained mechanical robustness with significant RhB adsorption even after three consecutive regeneration cycles signifying facile recycling. The nAg-AC displayed an outstanding efficacy for the real industrial wastewater depollution, indicating high effectiveness for practical environmental applications. Finally, the cost analysis (incorporating economic, environmental, and social dimensions) suggested a significant role of the nAg-AC in promoting and establishing sustainable development with the circular economy. |
Similar Articles
| ID | Score | Article |
|---|---|---|
27693
|
Shaikh, WA; Kumar, A; Chakraborty, S; Ul Islam, R; Bhattacharya, T; Biswas, JK Biochar-based nanocomposite from waste tea leaf for toxic dye removal: From facile fabrication to functional fitness(2022) | |
| 17136
|
Abdoul, HJ; Yi, MH; Prieto, M; Yue, HB; Ellis, GJ; Clark, JH; Budarin, VL; Shuttleworth, PS Efficient adsorption of bulky reactive dyes from water using sustainably-derived mesoporous carbons(2023) | |
| 16394
|
Devre, PV; Gore, AH Agro-Waste Valorization into Carbonaceous Eco-Hydrogel: A Circular Economy and Zero Waste Tactic for Doxorubicin Removal in Water/Wastewater(2023)Langmuir, 40, 1 | |
| 5540
|
Bendaoudi, AA; Boudouaia, N; Jellali, S; Benhafsa, FM; Bengharez, Z; Papamichael, I; Jeguirim, M Facile synthesis of double-cross-linked alginate-based hydrogel: Characterization and use in a context of circular economy for cationic dye removal(2024)Waste Management & Research, 42, 6 | |
| 21700
|
Samal, PP; Qaiyum, MA; Dutta, S; Mohanta, J; Dey, B; Dey, S Towards a circular economy: chemical packaging waste as a promising scavenger for Neutral red from water and wastewater(2023)International Journal Of Environmental Science And Technology, 20.0, 11 | |
| 9867
|
Choque-Quispe, D; Ligarda-Samanez, CA; Ramos-Pacheco, BS; Solano-Reynoso, AM; Quispe-Marcatoma, J; Choque-Quispe, Y; Peralta-Guevara, DE; Martínez-Huamán, EL; Correa-Cuba, O; Masco-Arriola, ML; Lechuga-Canal, WJ; Amanca, FM Formulation of Novel Composite (Activated Nanoclay/Hydrocolloid of Nostoc sphaericum) and Its Application in the Removal of Heavy Metals from Wastewater(2022)Polymers, 14.0, 14 | |
| 15803
|
Luhar, I; Luhar, S; Abdullah, MMA; Razak, RA; Vizureanu, P; Sandu, AV; Matasaru, PD A State-of-the-Art Review on Innovative Geopolymer Composites Designed for Water and Wastewater Treatment(2021)Materials, 14, 23 | |
| 7281
|
Priyanka; Vashisht, D; Taylor, MJ; Mehta, SK Evaluating the pre-treatment protocol required to produce an effective carbonized waste adsorbent for organic pollution control(2023) | |
| 27631
|
Nighojkar, A; Sangal, VK; Dixit, F; Kandasubramanian, B Sustainable conversion of saturated adsorbents (SAs) from wastewater into value-added products: future prospects and challenges with toxic per- and poly-fluoroalkyl substances (PFAS)(2022)Environmental Science And Pollution Research, 29.0, 52 | |
| 17199
|
Rattanawongwiboon, T; Khongbunya, N; Namvijit, K; Lertsarawut, P; Laksee, S; Hemvichian, K; Madrid, JF; Ummartyotin, S Eco-Friendly Dye Adsorbent from Poly(vinyl amine) Grafted Onto Bacterial Cellulose Sheet by Using Gamma Radiation-Induced Simultaneous Grafting and Base Hydrolysis(2024)Journal Of Polymers And The Environment, 32, 7 |