| Title |
Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2with Epoxides |
| ID_Doc |
14205 |
| Authors |
Paradiso, V; Capaccio, V; Lamparelli, DH; Capacchione, C |
| Title |
Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2with Epoxides |
| Year |
2020 |
| Published |
Catalysts, 10, 8 |
| DOI |
10.3390/catal10080825 |
| Abstract |
Coupling of CO(2)with epoxides is a green emerging alternative for the synthesis of cyclic organic carbonates (COC) and aliphatic polycarbonates (APC). The scope of this work is to provide a comprehensive overview of metal complexes having sulfur-containing ligands as homogeneous catalytic systems able to efficiently promote this transformation with a concise discussion of the most significant results. The crucial role of sulfur as the hemilabile ligand and its influence on the catalytic activity are highlighted as well. |
| Author Keywords |
homogeneous catalysis; sulfur; carbon dioxide; epoxides; cyclic carbonates; polycarbonates |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Science Citation Index Expanded (SCI-EXPANDED) |
| EID |
WOS:000567682000001 |
| WoS Category |
Chemistry, Physical |
| Research Area |
Chemistry |
| PDF |
https://www.mdpi.com/2073-4344/10/8/825/pdf
|