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Title Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples
ID_Doc 19214
Authors Elfadil, D; Della Pelle, F; Compagnone, D; Amine, A
Title Green Synthesis of Molecularly Imprinted Polymers for Dispersive Magnetic Solid-Phase Extraction of Erythrosine B Associated with Smartphone Detection in Food Samples
Year 2022
Published Materials, 15.0, 21
DOI 10.3390/ma15217653
Abstract Monitoring synthetic colorants in foods is important due to their potential toxicity and pathogenicity. We propose here a new and simple method for the extraction and determination of erythrosine B (ERT-B) in food samples. A composite of polydopamine-based molecularly imprinted polymers coating magnetic nanoparticles (Fe3O4@PDA@MIP) was synthesized using a green approach and exploited for the magnetic dispersive solid-phase extraction (MDSPE) of ERT-B. Fe3O4@PDA@MIP provides a rapid extraction of ERT-B, exhibiting good reusability and preconcentration ability. Moreover, the MIP showed a relatively good imprinting factor (3.0 +/- 0.05), demonstrating excellent selectivity against patent blue (an interfering dye) and other food matrix components. The proposed MDSPE was coupled to colorimetric smartphone-based detection that allowed us to obtain similar performances of UV-Vis spectroscopy detection. The smartphone-based optical detection facilitated the determination of ERT-B in the 0.5-10 mg/L range, with a limit of detection of 0.04 mg/L. The developed method was successfully employed to determine ERT-B in food samples (juice, candy, and candied cherries) with good recovery values (82-97%).
Author Keywords synthetic colorants; food samples; magnetic dispersive solid-phase extraction; polydopamine; molecularly imprinted polymers
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED)
EID WOS:000881175500001
WoS Category Chemistry, Physical; Materials Science, Multidisciplinary; Metallurgy & Metallurgical Engineering; Physics, Applied; Physics, Condensed Matter
Research Area Chemistry; Materials Science; Metallurgy & Metallurgical Engineering; Physics
PDF https://www.mdpi.com/1996-1944/15/21/7653/pdf?version=1667208257
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