| Title |
Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanism |
| ID_Doc |
24688 |
| Authors |
Vance, BC; Kots, PA; Wang, C; Granite, JE; Vlachos, DG |
| Title |
Ni/SiO2 catalysts for polyolefin deconstruction via the divergent hydrogenolysis mechanism |
| Year |
2023 |
| Published |
|
| DOI |
10.1016/j.apcatb.2022.122138 |
| Abstract |
Noble metal-based hydrogenolysis is emerging as a key chemical deconstruction technology of polyolefins into valuable products. Still, the catalyst cost and availability are significant barriers to handling the large volume of plastics. Cheap earth-abundant metals have been deemed inactive for polyolefin hydrogenolysis. Herein, we report that Ni/SiO2 is active in deconstructing low-density polyethylene to n-alkanes (C-6-C-35) at mild conditions (300 ?, 30 bar H-2) with maximum liquid yields of 65 wt%. We expose a new mechanism of long-alkane hydrogenolysis that encompasses chain location-dependent single and multiple C-C bond cracking events and rationalizes product selectivity and molecular weight dependence. Ni/SiO2 catalysts are reusable and can handle multiple plastics producing feedstock-dependent products (i.e., n-alkanes, iso-alkanes, cyclics, aromatics, etc.). The findings broaden the scope of viable catalysts polyolefin hydrogenolysis and unleash the potential to manage the volume of plastic waste. |
| Author Keywords |
Plastics waste; Hydrogenolysis; Nickel; Earth -abundant metals; Circular economy |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Science Citation Index Expanded (SCI-EXPANDED) |
| EID |
WOS:000884470500004 |
| WoS Category |
Chemistry, Physical; Engineering, Environmental; Engineering, Chemical |
| Research Area |
Chemistry; Engineering |
| PDF |
http://manuscript.elsevier.com/S0926337322010797/pdf/S0926337322010797.pdf
|