| Title |
Strengthening Regenerated Cellulose Fibers Sourced from Recycled Cotton T-Shirt Using Glucaric Acid for Antiplasticization |
| ID_Doc |
29942 |
| Authors |
Biswas, MC; Dwyer, R; Jimenez, J; Su, HC; Ford, E |
| Title |
Strengthening Regenerated Cellulose Fibers Sourced from Recycled Cotton T-Shirt Using Glucaric Acid for Antiplasticization |
| Year |
2021 |
| Published |
Polysaccharides, 2.0, 1 |
| DOI |
10.3390/polysaccharides2010010 |
| Abstract |
The recycling of cellulose from cotton textiles would minimize the use of virgin crop fibers, but recycled polymers are generally inferior in mechanical performance to those made from virgin resins. This challenge prompted the investigation of biobased additives that were capable of improving the mechanical properties of fibers by means of antiplasticizing additives. In this study, regenerated cellulose (RC) fibers were spun from cellulose found in cotton T-shirts, and fibers were mechanically strengthened with glucaric acid (GA), a nontoxic product of fermentation. The recycled pulp was activated using aqueous sodium hydroxide and then followed by acid neutralization, prior to the direct dissolution in lithium chloride/N,N-dimethylacetamide (LiCl/DMAc) at 3 wt.% cellulose. At 10% (w/w) GA, the tensile modulus and strength of regenerated cellulose from recycled cotton fibers increased five-fold in contrast to neat fibers without GA. The highest modulus and tenacity values of 664 cN/dtex and of 9.7 cN/dtex were reported for RC fibers containing GA. |
| Author Keywords |
antiplasticization; recycled cotton T-shirt; regenerated cellulosic fiber; bio-based additives; structure-property relationship; post-consumer waste; sustainability; circular economy |
| Index Keywords |
Index Keywords |
| Document Type |
Other |
| Open Access |
Open Access |
| Source |
Emerging Sources Citation Index (ESCI) |
| EID |
WOS:001109259100001 |
| WoS Category |
Polymer Science |
| Research Area |
Polymer Science |
| PDF |
https://www.mdpi.com/2673-4176/2/1/10/pdf?version=1614852746
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