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Title Assessment of Leaching Characteristics of Solidified Products Containing Secondary Alkaline Lead Slag
ID_Doc 9193
Authors Stulovic, M; Radovanovic, D; Kamberovic, Z; Korac, M; Andic, Z
Title Assessment of Leaching Characteristics of Solidified Products Containing Secondary Alkaline Lead Slag
Year 2019
Published International Journal Of Environmental Research And Public Health, 16.0, 11
DOI 10.3390/ijerph16112005
Abstract Reuse of waste is one of the main principles of sustainable development and circular economy. Secondary alkaline lead slag is a hazardous waste generated in the recycling process of lead-acid batteries that may be suitable in construction materials. The environmental impact of the use of lead slag as a partial replacement of fine aggregates in the cement-based stabilization/solidification (S/S) process for the preparation of concrete was studied in this paper. Solidified products containing 10%, 15%, 20%, and 25% slag were laboratory tested by unconfined compressive strength (UCS) analyses and the Toxicity Characteristic Leaching Procedure (TCLP). At the same time, the leachability of toxic elements from solidified products with a high percent of slag was evaluated under environmental conditions for during one year. The results of the UCS and TCLP indicated that utilization of this type of slag in cement-based applications may be justified with its controlled addition. However, the described application of the slag was disputed due to the high release of As under high alkaline environmental conditions. Eh-pH analyses and the geochemical modeling using the software PHREEQC were evaluated, as well as the mechanism of pollutant (Pb, As) immobilization (precipitation, adsorption) as a function of pH conditions.
Author Keywords slag; lead; arsenic; leaching; solidification; stabilization; geochemical modeling
Index Keywords Index Keywords
Document Type Other
Open Access Open Access
Source Science Citation Index Expanded (SCI-EXPANDED); Social Science Citation Index (SSCI)
EID WOS:000472132900133
WoS Category Environmental Sciences; Public, Environmental & Occupational Health
Research Area Environmental Sciences & Ecology; Public, Environmental & Occupational Health
PDF https://www.mdpi.com/1660-4601/16/11/2005/pdf?version=1559727744
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